Energetics of the interaction of the antitumour agent titanocene dichloride with glycine: enthalpy of formation of [Ti(ɳ5-C5H5)2(OOCCH2NH3)2]Cl2

Nunes, Paulo; Piedade, M.E.M.

http://hdl.handle.net/10400.15/4532

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Authors

Nunes, Paulo

Piedade, M.E.M.

Abstract(s)

The standard molar enthalpy of formation of [Ti(ɳ5-C5H5)2 (OOCCH2NH3)2]Cl2 in the crystalline state, at T = 298.15 K, was determined as DfHom{[Ti(ɳ5-C5H5)2(OOCCH2NH3)2]Cl2, cr} = -(1447.6 ± 8.1) kJ . mol-1, by reaction-solution calorimetry. A discussion of the energetics of the direct interaction of the antitumour agent Ti(ɳ5-C5H5)2Cl2 with glycine is also presented.

Keywords

enthalpy of formation thermochemistry reaction-solution calorimetry antitumour agents metallocenes

URI

http://hdl.handle.net/10400.15/4532

Citation

Nunes, P. & Piedade, M.E.M. (2004). Energetics of the interaction of the antitumour agent titanocene dichloride with glycine: enthalpy of formation of [Ti(ɳ5-C5H5)2(OOCCH2NH3)2]Cl2. Journal of Chemical Thermodynamics, 36(4), 321-323. DOI:10.1016/j.jct.2004.01.002